Electron paramagnetic resonance spectroscopic studies on the zero-valent rhodium complex [Rh(P(OPri)3)4] at X-and Q-band frequencies
✍ Scribed by G.N. George; S.I. Klein; J.F. Nixon
- Book ID
- 103024463
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 372 KB
- Volume
- 108
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
There itre rzlarively few tully st~~ttcturally cliirrwterised niononicric pilI4llliIgilc?liC X~~l-\fillellt cOIllpl~st?S d'tlw rypc ]hlL4) (hl = Co, Iih, Ir; L = ligand).
]Co(CO), ] is the best knowu esauiple 1 I 1, and nioiccular orbital calculations [?,3] predict that ii l&,t syniiiielry is slightly 1110nz favourcd than the alternative Cj,, structure. Infrared spectroscopic studies on a ma-Iris-isolated smple of [COG] were interpreted in term of the C,, structure 141, whereas a later detailed IR/Ran~an, UV/visihle and EI'R comparative study by Olin et al. [S ] indicated two isomcric forms having distorted C,, (low-telnperature preference, 6-S K) struct;resh' and D,, ( Ighel-trnlpcrature preference,