Electron paramagnetic resonance spectra of R-C60 radicals. Evidence for RC60C60R dimers
β Scribed by Morton, J. R.; Preston, K. F.; Krusic, P. J.; Wasserman, E.
- Book ID
- 121505004
- Publisher
- Royal Society of Chemistry
- Year
- 1992
- Tongue
- English
- Weight
- 533 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1472-779X
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π SIMILAR VOLUMES
Upon photo-and electrochemical in situ reduction of [ 60 ] fullerene derivatives, (n = 1, 2), C 60 [ C(COOEt) 2 ] n characteristic single-line EPR spectra are observed which are attributable to the corresponding radical anions. Monofunctionalized shows a reduction behavior similar to pristine i.e. f
## Abstract Oligothienylenevinylenes/C~60~ dyads **nβC** and triads **nβC**~**2**~ are studied by electrospray mass spectrometry. A clear correlation is observed between the nature of the charged species detected by mass spectrometry, i.e. protonated molecule [M + H], ^+^ cation radical M^+Β·^ and d