Electron mobilities and rate constants for electron-solute reactions in some non polar liquids
β Scribed by J. Casanovas; R. Grob; D. Grelot; D. Blanc; J. Mathieu
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 180 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0304-3886
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π SIMILAR VOLUMES
Electron capture rate constants for several solutes in isooctane, cyclohexane and n-hexane are reported. The method of measurement, which allows determination of the rate constants with an accuracy estimated to be better than 5%, involves the use of low power pulses of 337 nm light from a nitrogen l
It is shown how kinetic electron spin resonance spectroscopy with intermittent radical generation can be used to obtain rate constants of various simultaneous reactions in systems containing more than one kind of transient radicals. The technique is applied to reactions of tert-butyl [(CH, )& and is
ee f?rward and rcvetx rates of the reaction CO2 '+ e---' COT were determined in tetramethylsilane, neopentane and '. ?,2,4-trimethylpente as a function of tempcntue. The forward reaction is exothermic in solution but the equilibrium constant skf?s over four &hers of magnitude with changes in solve