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Electron Localization versus Delocalization and Ferromagnetic Coupling in Mixed Valence Polyoxometalates

✍ Scribed by Serguei A. Borshch; Ekaterina M. Zueva

Publisher
Springer
Year
2006
Tongue
English
Weight
208 KB
Volume
116
Category
Article
ISSN
1432-2234

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## Abstract We present here a general theoretical procedure to treat the problem of electron delocalization and magnetic interactions in high‐nuclearity mixed valence clusters based on polyoxometalates. The main interactions between the delocalized electrons of mixed‐valence polyoxometalate anions