Electron impact study of carbon disulphide micro-clusters
β Scribed by Andrzej Pelc; Leszek Michalak
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 487 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0042-207X
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β¦ Synopsis
The production of carbon disulphide micro-clusters (CS ) L , n)11, by adiabatic gas expansion of mixture of CS vapour and Ar is studied by using an electron impact ion source and a double focusing sector field mass spectrometer. The appearance potentials for clusters n)9 decreased as n increased but was not a simple function of 1/n. The appearance pressures of observed clusters showed a slowly increasing dependence on cluster size. Results of measurements of appearance potentials and appearance pressures of selected clusters are described for a range of operating conditions.
π SIMILAR VOLUMES
The dynamics of cluster ions following electron impact ionization of Ar n, n = 3, 4, have been modelled theoretically and the calculated fragmentation probabilities compared with recent measurements using scattering deflection techniques. The calculations have been conducted using a hybrid quantum/c