Electron-impact studies—LI: Hydrogen randomization in the stilbene molecular ion
✍ Scribed by P. F. Donaghue; P. Y. White; J. H. Bowie; B. D. Roney; H. J. Rodda
- Publisher
- John Wiley and Sons
- Year
- 1969
- Tongue
- English
- Weight
- 301 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1076-5174
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## Abstract In the electron impact mass spectra of some alkyl α‐ and β‐hydroxyesters (introduced using the gas chromatography/mass spectrometry (GC/MS) technique), the absence of the molecular ion M^+·^ and the presence of the [M + 1]^+^ ion instead is observed. This phenomenon is especially charac
Laser desorption of neutral molecules followed by electron impact ionization is shown to produce gaseous ion radicals that undergo fragmentation analogous to that observed with electron impact and field ionization. Spectra were measured of heptanal and four deuterium-labeled analogs regenerated from