✦ LIBER ✦

Electron Impact Mass Spectra of Carbonyl Hydrazones of o-Aminoaryl Ketones

✍ Scribed by Antigoni Kotali

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 130 KB
Volume: 10
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(19960715)10:9<1113::aid-rcm590>3.0.co;2-g

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✦ Synopsis

The title compounds are prepared from the reaction of o-aminoaryl ketones with hydrazides. Their electron impact mass spectra are reported. In addition to the molecular ion, characteristic peaks appear at values corresponding to the [M -NHJ, [M -NHCOX]' and [M -COX]' ions.

Recently, we reported the synthesis of 0-aminoaryl ketone acylhydrazones 1 along with their oxidative cyclization to 2acylaminoindazoles, on treatment with lead(1V)acetate.

Continuing our interest in the nitrogen derivatives of carbonyl compounds and especially in their behaviour in mass spectrometry, we now report their electron-impact mass spectra.

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