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Electron-impact induced skeletal re-arrangement of 2-methoxy-3-methylpyrazine and 2-methylthio-3-methylpyrazine

✍ Scribed by Michael G. Kolor; Donald J. Rizzo


Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
401 KB
Volume
5
Category
Article
ISSN
1076-5174

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C-8-substituted N-methyl-l,2,3,4-tetrahydroisoquinoline radical cations lose the complete substituent in a one step reactlion giving rise to an unexpected ion at m/z 146, which is probably identical with the dihydroisoindolylmethylcation A. The dihydroisoindoles 1. 10, and 16 were prepared as potent