The fragmentation behaviour of 18 vicinally substituted aminonitropyridines was studied under electron impact conditions. The decomposition patterns were found to be strongly dependent on the position of substituents The formation of the am analogue of carbazole seems phenylamioopyridine.
Electron-impact-induced fragmentation of some diterpenoid acetals
โ Scribed by R. C. Cambie; A. F. Preston; P. D. Woodgate
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 422 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1076-5174
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โฆ Synopsis
Abstract
Study of the low and highโresolution mass spectra of a series of diterpenoid acetals, including both positional isomers and stereoisomers, has permitted the proposal of some characteristic fragmentation pathways leading to analytically distinctive peaks. The mass spectrum was particularly informative in the assignment of structure to an unexpected rearrangement product (V).
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