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Electron Impact Fragmentation of Mixed and Asymmetric Benzyltin Compounds

✍ Scribed by Marcel Gielen

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
242 KB
Volume
94
Category
Article
ISSN
0037-9646

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✦ Synopsis

The mass spectra of seventeen mixed and of five asyPrPetric benzyltin cornpounds are described and analyaed. The proposed fragmentation pattern in in agreement with the hypothesis of preferred Sn(IV) and Sn(I1) valence states in the tin-containing fragments, which are reached by a loss of a radical from the molecular ion, or by the loss of an alkene or alkane from a favourable valence state.

πŸ“œ SIMILAR VOLUMES

Electron impact fragmentation of some mi
Electron impact fragmentation of some mixed cyclotetraphosphazenes
✍ T. Tunde Bamgboye; Omolara A. Bamgboye πŸ“‚ Article πŸ“… 1985 πŸ› John Wiley and Sons 🌐 English βš– 448 KB

The electron impact fragmentations of some cyclotetraphosphazenes are reported and discussed. The major fragmentation path involves loss of two amine radicals and one chlorine radical in the series PfiN,Ck,(NMe2), when n = 2, and subsequent stages involve a ring contraction process with elimination