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Electron exchange between tris(hexafluoroacetylacetonato)ruthenium(II) and (III) and between related compounds. Effects of solvent on the rates

โœ Scribed by Chan, Man Sheung; Wahl, Arthur C.


Book ID
120421429
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
702 KB
Volume
86
Category
Article
ISSN
0022-3654

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The rate of the electron-exchange betwee
โœ I. Ruff; M. Zimonyi ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 193 KB

The rate of the electron-exchange between ferroin and ferriin ions, unmeasurably fast for methods known so far, has been determined by the application of transfer diffusion. The second order rate constant proved to be (3.3 f 1.4) x lOs/M/s. The rate constant calculated by accounting for the electros