## Abstract Five new nitrogen‐oxygen mixed donor macrocycles have been prepared by condensation of 2,6‐bis [(2‐formylphenyl)oxymethyl]pyridine with different diamino compounds in hot methanol, followed by a one‐pot reduction of the intermediate bis‐Schiff base. All the macrocycles were identified b
✦ LIBER ✦
Electron-donor properties of the pyridine 1-oxide ring
✍ Scribed by A. R. Katritzky
- Book ID
- 104586117
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 166 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
Available evidence for the electron‐donor properties of the pyridine and pyridine 1‐oxide rings is briefly reviewed. The positions and intensities of the CN stretching band in cyano‐pyridines and ‐pyridine 1‐oxides confirms that electron availability in the pyridine ring decreases at the nuclear positions in the order 3≫4>2 and in the pyridine 1‐oxide ring in the order 4 ≫ 3 ∼ 2.
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