✦ LIBER ✦
Electron donor-acceptor complexes of polyoxometalates with organic molecules. Picosecond spectroscopy of [(N-methylpyrrolidinone)2H+PW 12O403−
✍ Scribed by J.A. Schmidt; E.F. Hilinski; D.A. Bouchard; C.L. Hill
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 590 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The photochemistry of the electron donor-acceptor complex formed between N-methylpyrrolidinone and H3PW,2040 was investigated by means of picosecond absorption spectroscopy.
Excitation at 355 nm generates PWj20& within ~90 ps after excitation. Evidence exists for the production of a species within the time duration of the excitation laser pulse which either gives rise to or exists with PW,,O& .