Thermochemical analysis of the electron capture process of SFs leads to a rate constant for the reverse process SF; 2 SF6 + e-, k 2 = 1.5 X 1013-31'.4/H s-l, where 0 = 2.303RT, in kcal/mol. The electron affinity of 32 f 3 kcal/mol is deduced from the observed bimolecularity of the capture process do
Electron distribution functions for electron attachment to SF6 and model systems
β Scribed by B. Shizgal
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 497 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The steady electron distribution function in attaching gases can be strongly perturbed from the thermal Maxwellian or Davydov distributions. For particular cross sections, concentrations and electric fields, the steady electron distribution can be localized at high energies. A very efficient methodology for the calculation of the electron distribution as the lowest eigenfunction of the appropriate Fokker-Planck equation (or equivalent SchriSdinger equation) has been developed. Results are presented for a model system, and for SF, in He and Xe. The eigenvalue spectrum of the Fokker-Planck equation determines the time evolution of electron properties, and the extent to which the attachment and thermalization processes are coupled.
π SIMILAR VOLUMES
Experimental datz are presented which provide 2 comparison of the electron energy dlstrrhution functions for the gases C9H4, N9 and Ar. used in electron attachment studies. Standard carrier gases for swarm studies alone or combined with electron beam data are recommended.