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Electron Density and Charge Distribution around the Metal Atom in [Cp*Fe(η5-As5)]

✍ Scribed by Rolfe H. Herber; Otto J. Scherer

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
227 KB
Volume
2000
Category
Article
ISSN
1434-1948

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✦ Synopsis

57 Fe Mössbauer effect spectroscopy has been used to study the charge density, charge distribution, and lattice dynamics in the ferrocene-related compound [Cp*Fe(η 5 -As 5 )]. The isomer shift (at 90 K) is significantly more positive than that observed for the related η 5 -P 5 homologue reported earlier, while the quadrupole hyperfine interaction is essentially the same in both compounds, but only about a quarter of that [a]

📜 SIMILAR VOLUMES

The Transition Metal Complex (η5-C5H5)Fe
The Transition Metal Complex (η5-C5H5)Fe(CO)2Cl in Its Neutral, Anionic, and Cationic States—Density Functional Theory Calculations and Mass Spectroscopical Investigations
✍ A. Vierheilig; D. Moigno; W. Kiefer; A. Materny 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 174 KB

In this contribution, we report density functional theory calculations on the transition metal complex (η 5 -C 5 H 5 )Fe(CO) 2 Cl and its fragments in differently charged states (anionic, neutral, cationic). The results are compared to literature data. The work is motivated by the long-term objectiv