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Electron delocalization in ilvaite, a reinterpretation of its57Fe Mössbauer spectrum

✍ Scribed by F. J. Litterst; G. Amthauer


Publisher
Springer-Verlag
Year
1984
Tongue
English
Weight
611 KB
Volume
10
Category
Article
ISSN
0342-1791

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Phase transitions in ilvaite, a mixed-va
✍ Kan Xuemin; Subrata Ghose; B. D. Dunlap 📂 Article 📅 1988 🏛 Springer-Verlag 🌐 English ⚖ 556 KB

llvaite, Ca (Fe 2 +,Fe 3 +)Fez + Si208(OH) shows two magnetic phase transitions, which have been studied by M6ssbauer spectroscopy within the temperature range 120-4 K. The continued charge localization between Fe 2+ and Fe 3 + ions in octahedral A-sites causes the Fe 2 + -Fe 3 + interaction to be f