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Electron-Deficient Vanadium(III) Alkyl and Allyl Complexes with Amidinate Ancillary Ligands †

✍ Scribed by Brussee, Edward A. C.; Meetsma, Auke; Hessen, Bart; Teuben, Jan H.

Book ID
126227091
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
109 KB
Volume
17
Category
Article
ISSN
0276-7333

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An Amidinate Ligand with a Pendant Amine
An Amidinate Ligand with a Pendant Amine Functionality; Synthesis of a Vanadium(III) Complex and Ethene Polymerization Catalysis[#]
✍ Menno J. R. Brandsma; Edward A. C. Brussee; Auke Meetsma; Bart Hessen; Jan H. Te 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 92 KB 👁 2 views

A new type of amidinate ancillary ligand has been prepared, distortion of the amidinate nitrogen bearing the pendant functionality. With AlEt 2 Cl cocatalyst the compound 1 which incorporates a pendant tertiary amine functionality. The crystal structure of a vanadium(III) derivative, produces a sing