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Electron correlation and relative energetic characteristics of complex hydrides of light elements. I. Beryllohydrides

✍ Scribed by R. Cimiraglia; M. Persico; J. Tomasi; O. P. Charkin


Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
667 KB
Volume
5
Category
Article
ISSN
0192-8651

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✦ Synopsis


The effect of correlation energy on the relative stability of different structures and dissociation products of complex lithium beryllohydrides has been investigated. The adequacy of the method employed (third-order Moller-Plesset perturbation theory) and the basis set dependence have been assessed. Trends of the correlation energy according to the molecular structure have been discussed, and the validity of an additive scheme based on electron pair contributions has been tested.