Electron capture by haloethanes in a carbon dioxide buffer gas

✍ Scribed by A. Rosa; W. Barszczewska; M. Foryś; I. Szamrej

• Publisher: Elsevier Science
• Year: 2001
• Tongue: English
• Weight: 192 KB
• Volume: 205
• Category: Article
• ISSN: 1387-3806
• DOI: 10.1016/s1387-3806(00)00281-5

✦ Synopsis

An electron swarm method for investigation of the electron capture reaction has been modified. It is based on the registration of the temporal evolution of a single electron pulse. The method gives straightforward results on electron drift velocities in any mixture and allows calculating the rate constants for the electron capture. The thermal electron capture kinetics for eight haloethanes has been investigated. Only two-body attachment processes have been found in their mixtures with carbon dioxide. All corresponding rate constants have been determined. A link between the two-body rate constant and an electron polarizability of the attaching center has been demonstrated. (Int J Mass Spectrom 205 (2001) 85-92) © 2001 Elsevier Science B.V.