Electron-Capture and -Transfer Dissociation of Peptides Tagged with Tunable Fixed-Charge Groups: Structures and Dissociation Energetics
✍ Scribed by Thomas W. Chung; Christopher L. Moss; Magdalena Zimnicka; Richard S. Johnson; Robert L. Moritz; František Tureček
- Book ID
- 107700588
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 1016 KB
- Volume
- 22
- Category
- Article
- ISSN
- 1044-0305
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## Abstract Electron‐induced dissociations of gas‐phase ternary copper‐2,2′‐bipyridine complexes of Gly‐Gly‐Gly and Gly‐Gly‐Leu were studied on a time scale ranging from 130 ns to several milliseconds using a combination of charge‐reversal (^+^CR^−^) and electron‐capture‐induced dissociation (ECID)
## Abstract Transition metal cations Co^2+^, Ni^2+^ and Zn^2+^ form 1 : 1 : 1 ternary complexes with 2,2′‐bipyridine (bpy) and peptides in aqueous methanol solutions that have been studied for tripeptides GGG and GGL. Electrospray ionization of these solutions produced singly charged [Metal(bpy)(pe