Electromagnetic moments and fields induced by nuclear spin, vibrational electric and magnetic field at the nuclei, and nuclear electromagnetic couplings in molecules

14N- and D-nuclear quadrupole coupling i

14N- and D-nuclear quadrupole coupling in the rotational spectrum of (CH3)314N…H(D)F: Modification of the electric field gradients at the N and D nuclei

✍ A.C. Legon; C.A. Rego 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 620 KB

Ground-staterotational spectra ofthe isotopomers (CH,)9'4N...HFand (CH,),'4N...DFofthe trimethylamine-hydrogen fluoride dimer have been analysed to give spectroscopic constants, including the 14N and D nuclear quadrupole coupling constants, x0.( "'N) and x,~( D), respectively. The changes of these c