Electrolytic reductive coupling as a synthetic tool
โ Scribed by M.M. Baizer; J.D. Anderson; J.H. Wagenknecht; M.R. Ort; J.P. Petrovich
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 373 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
โฆ Synopsis
Abstmct-The utility of electrolytic reductive cou functional compounds is discussed. &Is Activated ole ling as a means for synthesizing a variety of polyfunction as acceptors towards donors generated by electrolytic reduction of (a) other activated ok&s, (b) other activated olefinic groups within the same molecule, (c) compounds containing "leaving groups" and (d) azo-compounds and Schiff bases. R&mm&On diiute l'utilite du couplage &ctrolytique r&ductif comme moyen de synthese d'une multitude de co "$a os6s polyfonctionnels. Lo3 ol&nes activtes fonctionnent comme accepteurs envers les domxxus pro urts par la reduction 6lectrolytique: (a) des autres 016fmes activ&zs, (b) des au&s groupes ol&iniques actives dans les memes mol&x&s, (c) des compos6s contenant des "leaving groups" et (d) des compods azo et des bases de S&8. Z-Die Verwendbarkeit der elektrolytischen reduktiven Ku pelung als ein Synthesemittel ftir die Darstelhmg von verschieden polyfunktionellen Verbm ungen wird erotert. *B Aktivierte Olefine dienen als Akzeptoren fiir die Donatoren, die durch elektrolytische Reduktion von (a) anderen aktivierten Olefinen, (b) anderen aktivierten olefinischen Gruppen hmerhalb desselben Molekiils, (c) "leaving groups" enthaltenden Verbmdungen und (d) Azoverbmdungen und Schiffschen Basen gebildet werden.
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