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Electrolytic Preparation of Vanadium(V) Oxide from Saturated Solutions of Ammonium Metavanadate

✍ Scribed by V. M. Nagirnyi; R. D. Apostolova; A. S. Baskevich; P. M. Litvin; E. M. Shembel'


Book ID
110323677
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
66 KB
Volume
74
Category
Article
ISSN
1070-4272

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Vanadium pentoxide gels are formed via the reaction of V 2 O 5 powder with hydrogen peroxide. 51 V NMR studies of the solution show that the dissolution of the oxide leads to the formation of solute diperoxo [VO(O 2 ) 2 ] ؊ species. These peroxo species are not stable in the solution. They progressi