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Electrolytic Partial Fluorination of Organic Compounds. Part 84. Anodic Mono- and Difluoronation of Benzylphosphonate Derivatives.

โœ Scribed by Bakenova Zagipa; Asami Hidaka; Yi Cao; Toshio Fuchigami


Book ID
101991224
Publisher
John Wiley and Sons
Year
2006
Weight
17 KB
Volume
37
Category
Article
ISSN
0931-7597

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Electrolytic partial fluorination of org
โœ Toshiki Tajima; Hideki Ishii; Toshio Fuchigami ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 68 KB

Anodic fluorination of 2-cyano-1-methylpyrrole using Et 3 Nโ€ข2HF in an undivided cell provided the corresponding 5-fluoropyrrole and 2,5,5-trifluoro-1-methyl-3-pyrrolin-2-carbonitrile while the use of Et 3 Nโ€ข3HF afforded selectively the latter product, which was readily hydrolyzed to isolable 5,5-dif