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Electrolytic partial fluorination of organic compounds. 3. Regioselective anodic monofluorination of organoselenium compounds and their synthetic application

โœ Scribed by Toshio Fuchigami; Toshiaki Hayashi; Konno Akinori

Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
284 KB
Volume
33
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Regioselective anodic a-monofluorination of selenides bearing electron-withdrawing groups such as cyano, ester, and amide groups was successfully performed. Highly stereoselective synthesis of a-fluoro o&unsaturated esters was achieved by using an a-fluoro a-selenoester prepared.

Recently, much interest has been paid to partially fluorinated compounds in the fields of material science and medicinal chemisuy." However, methodes for their preparation are limited in many cases3'

๐Ÿ“œ SIMILAR VOLUMES

Electrolytic partial fluorination of org
Electrolytic partial fluorination of organic compounds. Part 45: Highly regioselective anodic monofluorination of (E)-3-benzylidene-2,3-dihydrochroman-4-ones
โœ Kamal M Dawood; Toshio Fuchigami ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 68 KB

Anodic monofluorination at the position a to the oxygen atom of chroman-4-one derivatives was successfully carried out: this is the first selective electrochemical fluorination of fused-type, oxygen-containing heterocyclic compounds.