✦ LIBER ✦
Electrolytic fixation of CO2 by electrocarboxylation of rx on nanocrystalline TiO2-Pt cathode
✍ Scribed by Dao-Bao Chu; Xiao-Hua Li; Xin-Yuan Liu; Wen-Li Yao
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 359 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0256-7660
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✦ Synopsis
Abstract
Electrolytic fixation of CO~2~ was investigated by electrocarboxylation of organic halides (a), and four esters (I, II, III, IV) were obtained in moderate yields. Electrochemical reduction esterifications of RX in the presence of CO~2~ were carried out on nanocrystalline TiO~2~‐Pt electrode. The electrochemical behavior of RX in the presence of CO~2~ was investigated by the technique of cyclic voltammetry, and the probable reaction mechanism was proposed.