Electrohydrodimerization of 4,4-dimethyl-2-cyclohexen-1-one in dimethylformamide on a mercury electrode
β Scribed by R.M. Bastida; E. Brillas; J.M. Costa
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 537 KB
- Volume
- 227
- Category
- Article
- ISSN
- 0022-0728
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π SIMILAR VOLUMES
## Abstract The parameters which influence the inverted wave appearing in the reverse (oxidation) sweep in the cyclic voltammogramme of the title compound **1** are discussed in detail. The inverted wave is due to the interaction of the reduction products of **1** with the electrode and the electro
## Abstract The title compound __R__β4a was prepared from (β)βquinic acid (1) in 6 steps in 18% overall yield (Scheme 3) and with 100% enantiomeric purity (Figure 1). The initiating step is the regioβ and stereoselective acetalization of the __trans__βoriented vicinal OH groups of 1 (+ 5 β 8). Alco