Electrogenerated-bases promoted electrochemical synthesis of N-bromoamino acids from imines and carbon dioxide
β Scribed by Li, Chuan-Hua; Song, Xiang-Zhi; Tao, Li-Ming; Li, Qiang-Guo; Xie, Jin-Qi; Peng, Meng-Na; Pan, Lan; Jiang, Chao; Peng, Zhi-Yu; Xu, Man-Fen
- Book ID
- 125418616
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- French
- Weight
- 672 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0040-4020
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Caught in the act: N-Heterocyclic carbene copper(I) complexes (1; IPr=1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) serve as an excellent catalyst for the carboxylation of alkylboranes (2; R=alkyl) with CO(2) to afford a variety of functionalized carboxylic acids (3) in high yields. A novel copp
## Abstract A broad spectrum of substrates bearing a free allyl moiety can be transformed to carboxylic acids in good to excellent yields and various functionalities are tolerated.