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Electrodimerization IV. Formation of substituted pinacols in the reduction of α-substituted carbonyl compounds

✍ Scribed by C.P. Andrieux; J.M. Savéant

Book ID
104148496
Publisher
Elsevier Science
Year
1970
Weight
288 KB
Volume
28
Category
Article
ISSN
0022-0728

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✦ Synopsis

The electroreduction of a wide variety of aldehydes and ketones substituted on an a aliphatic o r alicyclic carbon has been previously studied. The parent carbonyl compounds were aryl alkyl ketones 1-12 , aliphatic aldehydes and ketones 1!-19 (see also ref. 9 and references therein) and alicyclic ketones 2°-26 . The substituting groups considered were the following:

📜 SIMILAR VOLUMES

Conformational studies of α-substituted
Conformational studies of α-substituted carbonyl compounds—V. Evidence for hyperconjugative interactions in 2-iodosubstituted carbonyl systems. ω-iodo-p-substituted acetophenones
✍ P.R. Olivato; S.A. Guerrero; P.S. Santos 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 544 KB

The infrared carbonyl stretching (vco) frequencies as well as the carbon-iodine (vc\_,) Raman and infrared frequencies for some w-iodo-p-substituted acetophenones are reported. Although in the title compounds the solvent effect on the carbonyl band does not indicate the existence of cis/gauche rotat

The formation of tricarbonyl-substituted
The formation of tricarbonyl-substituted aromatic compounds from carbonyl-substituted olefins by palladium(II) salts in the presence of sodium acetate
✍ Tsutomu Sakakibara; Shigehiro Nishimura; Koji Kimura; Sonoo Fujioka; Yoshinobu O 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 215 KB

In the previous paper&, we described the formation of cinnamic acid derivatives from saturated aliphatic acids and aromatic compounds by palladium (II) salts. In the course of further investigation of these reactions, we found