Electrode processes of ammonium ion and its complexes with macrocyclic ligands in propylene carbonate and acetonitrile
✍ Scribed by K. Angelis; M. Březina; J. Koryta
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 185 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-0728
No coin nor oath required. For personal study only.
✦ Synopsis
Electroreduction of the ammonium ion at the DME was first described by Heyrovsk~A. Vl~ek 2 found that the ammonium amalgam gave~no d.c. polarographic wave which would correspond to ammonium oxidation while a reversible reduction and oxidation process was observed with Heyrovsk~, 'S a.c. oscillographic polarography (cf. also ref. 3). No electrode processes of ammonium ion complexes have been reported so far.
📜 SIMILAR VOLUMES
The conductance of sodium and potassium tetraphenylborate and picrate complexes with bis(Q tert-butylbenzo)-l8-crown-6 (mtbDBC) and bis(3.Sdi-tert-butyIbenzo)-18-crown-6 (dtbDBC) in acetonitrile solutions at 25°C was analysed according to the Fuoss-Hsia equation. Values of the limiting
The response of an ion sensor consisting of polyacrylamide (PAA) coupled to benzo-15crown-5 (BlSCS) to sodium, potassium, magnesium, calcium and barium ions in propylene carbonate (PC) were investigated. The PAA-BlSC5 electrode showed a Nemstian response to sodium and calcium ions in PC. The electro