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Electrocyclization of (Z)-1,2,4,6-Heptatetraene and its Heterosubstituted Analogues: Pericyclic or Pseudopericyclic?

✍ Scribed by Jesús Rodríguez -Otero; Enrique M. Cabaleiro-Lago

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
156 KB
Volume
41
Category
Article
ISSN
0044-8249

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A Density Functional Theory Study on the
A Density Functional Theory Study on the Electrocyclization of 1,2,4,6-Heptatetraene Analogues: Converting a Pericyclic to a Pseudopericyclic Reaction
✍ Enrique M. Cabaleiro-Lago; Jesús Rodríguez-Otero; Rosa M. García-López; Angeles 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 340 KB 👁 1 views

## Abstract A comprehensive B3LYP/6‐31+G\* study on the electrocyclization of 1,2,4,6‐heptatetraene analogues was conducted. Starting from the cyclization of (2__Z__)‐2,4,5‐hexatrienal, a pericyclic disrotatory process favored by the assistance of a electron lone pair, we incorporated small modific