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Electrocondensation polymers: Electrochemical condensation of aromatic diacetyl compounds

✍ Scribed by Laube, Bruce L. ;Higgins, Jerry

Publisher
Wiley (John Wiley & Sons)
Year
1972
Tongue
English
Weight
791 KB
Volume
10
Category
Article
ISSN
0449-296X

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✦ Synopsis

Abstract

Electrochemical reduction of 4,4β€²,‐diacetyldiphenylethane at mercury in 80% ethanol/1__M__ potassium acetate produced the pinacols in high yield by the one‐electron/one proton reduction of the carbonyl groups. Although polarographic analysis indicated essentially complete conversion to pinacol, the low inherent viscosities of 0.03–0.06 of the polypinacols implied the presence primarily of oligomers.

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