✦ LIBER ✦
Electrochemistry in aprotic solvents containing anhydrous perchloric acid: Electroreduction behavior of quinones
✍ Scribed by Kadir Pekmez; Muzaffer Can; Attila Yildiz
- Book ID
- 103064606
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 475 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0013-4686
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✦ Synopsis
A--The electroreduction behavior of four quinones in acetonitrile in the presence and absence of anhydrous perchloric acid was investigated. The anhydrous perchloric acid was prepared by the electrooxidation of the dissolved molecular hydrogen in the same medium. The results of the cyclic voltammetric and the controikd potential electrolysis experiments were used in proposing the me&a&m of the electroreduction. It was established that the use of an anhydrous strong proton donor revealed more details in the electroreduction mechanism of the quinonts.