Electrochemistry applied to thermal conversion

• Book ID: 103898037
• Publisher: Elsevier Science
• Year: 1984
• Tongue: English
• Weight: 238 KB
• Volume: 11
• Category: Article
• ISSN: 0378-7753
• DOI: 10.1016/0378-7753(84)87039-1

✦ Synopsis

l kinetics of the O2 reduction will be examined as functions of coverage of substrate structures with the adsorbed macrocycles. This will be accomplished by following the increase in current for O2 reduction with the macrocyclic (water-soluble form) adsorption on the electrode. (Or in the case of nonsoluble forms, the coverage is varied by controlling the preapplication conditions.) Over the next 2 years, EXAFS studies of the most promising macrocycles on carbon will be undertaken. This work will be supported with molecular orbital calculations of O2 interactions with the transition metal macrocycles.