✦ LIBER ✦

Electrochemistry and electrogenerated chemiluminescence of films of the conjugated polymer 4-methoxy-(2-ethylhexoxyl)-2,5-polyphenylenevinylene

✍ Scribed by Mark M. Richter; Fu-Ren F. Fan; Floyd Klavetter; Alan J. Heeger; Allen J. Bard

Book ID: 103030402
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 301 KB
Volume: 226
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)00716-0

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✦ Synopsis

The thin fdm electrochemistry and electrogenerated chemiluminescence (ECL) of the title compound were obtained on Pt electrodes (CH3CN/0.1 M tetrabutylammonium fluoroborate). Orange luminescence (~ m~ = 622 nm) was obtained by pulsing the potentials between + 0.40 and -2.35 V versus Fc/Fc + as well as by oxidizing the system in the presence of TPAH (TPAH = trin-propylamine), which generates the strongly reducing intermediate TPA', and by reducing the system in the presence of $2 02-, which produces the strongly oxidizing intermediate SO~-".

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