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Electrochemically reduced tungsten-based active species as catalysts for metathesis-related reactions: ring-opening metathesis copolymerization of cyclopentene with cyclooctene

✍ Scribed by Solmaz Karabulut; Sevil Çetinkaya; Yavuz İmamoǧlu

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
117 KB
Volume
19
Category
Article
ISSN
0268-2605

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Electrochemically generated tungsten-based active species as catalysts for metathesis-related reactions: 1. Acyclic diene metathesis polymerization of 1,9-decadiene
✍ Okan Dereli; Bülent Düz; Birgül Zümreoğlu-Karan; Yavuz İmamoğlu 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 128 KB 👁 1 views

## Abstract The application of the WCl~6~–e^−^–Al–CH~2~Cl~2~ system to acyclic diene metathesis polymerization of 1,9‐decadiene is reported. The polyoctenamer formed is of a weight‐average molecular weight of 9000 with a polydispersity of 1.92. IR and NMR spectral analyses indicate the retention of