Electrochemically induced silylation of unsaturated compounds

✍ Scribed by V. Jouikov; L. Grigorieva

• Book ID: 103067646
• Publisher: Elsevier Science
• Year: 1996
• Tongue: English
• Weight: 189 KB
• Volume: 41
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/0013-4686(95)00325-8

✦ Synopsis

Electroreduction of some alkylchlorosilanes

in the presence of diff&lt to reduce unsaturated compounds (phenylacetylene, styrene, cyclohexene) results in silylated products where the multiple bond has either reduced multiplicity (hydrosilylation) or the same multiplicity (silylation) depending on the nature of the starting compounds and conditions of electrolysis.