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Electrochemical Synthesis of the Sex Attractant Pheromone of the Housefly: (Z)-9-Tricosene

✍ Scribed by Ashok K. Yadav; Paul Tissot


Publisher
John Wiley and Sons
Year
1984
Tongue
German
Weight
259 KB
Volume
67
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The electrochemical synthesis of muscalure, (Z)‐9‐tricosene(1), has been carried out by coelectrolysis of erucic acid (2) and propionic acid (3) in an undivided cell in methanol. To optimize the yield of the cross coupled product 1, the reaction has been studied in detail by varing different parameters, viz., electrode material, current density, molar ratio of 2 to 3, degree of partial neutralization and quantity of water in methanol.


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Sex attractant pheromone of the pecan nu
✍ Jocelyn G. Millar; Allen E. Knudson; J.Steven McElfresh; Regine Gries; Gerhard G πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 988 KB

A female-produced sex pheromone for the pecan nut casebearer, Acrobasis nuxvorella Neunzig, has been identified from pheromone gland extracts of calling female moths. The compound (9E,11Z)-hexadecadienal [(9E,11Z)-16:Ald] was identified by coupled GC-EAD and retention time matches with a synthetic s