Electrochemical synthesis of new polymeric reagents

✍ Scribed by R. Tabaković; E. Gunić; I. Tabaković; M. Zupan

• Publisher: Elsevier Science
• Year: 1992
• Tongue: English
• Weight: 451 KB
• Volume: 37
• Category: Article
• ISSN: 0013-4686
• DOI: 10.1016/0013-4686(92)80080-6

✦ Synopsis

Abatraet-Crossbnked poly [styrene4vmyl (N-metbylpyndmmm lo&de)] (1MaPVPI), poly [styrene4 vmyl (pmdmmm hydrolotide)] (PVPHI) and denvatwes were transformed to new polymenc reagents, dlffermg m amons, by usmg a supportmg electrolyte carrymg the desired amon through antic oxuiation of the released lo&de at a controlled potential The exchange reachon was studied by means of electroanalflcal tecbmques A new and simple electrochenucal method for the syntbes~s of oxldmng, reducmg, nucleopiubc and acldlc polymenc reagents IS described Key words synthesis of polymenc reagents, polyvmylpyndmmm iodide denvatwes, amon exchange