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Electrochemical study of the effect of axial coordination upon the redox behavior of iron porphyrins in dimethylformamide

✍ Scribed by D. Lexa; M. Momenteau; J. Mispelter; J.M. Lhoste

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
755 KB
Volume
1
Category
Article
ISSN
1567-5394

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## Abstract The effect of axial ligands on the reactivity of high‐valent iron(IV) oxo‐porphyrins (Compound I) was investigated using the B3LYP hybrid density functional method. We studied alkane hydroxylation using four models: Compound I with thiolate, imidazole, phenolate, and chloride anions as