Electrochemical study of intercalated vanadyl phosphate
✍ Scribed by N. Dupré; J. Gaubicher; J. Angenault; M. Quarton
- Publisher
- Springer
- Year
- 2004
- Tongue
- English
- Weight
- 321 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1432-8488
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Intercalates of VOPO 4 with several aliphatic aldehydes, benzaldehyde, and 4-methylbenzaldehyde were prepared and characterized by thermogravimetric analysis, X-ray di4ractometry, and IR and UV+vis spectroscopies. Aliphatic aldehyde intercalates are unstable and the guests undergo aldol condensation
Structure analysis of vanadyl phosphate intercalated with acetone has been carried out using a combination of X-ray powder di4raction, infrared spectroscopy, and molecular mechanics simulations in Cerius 2 modeling environment. IR spectroscopy revealed the tautomerism in the interlayer space of VOPO