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Electrochemical reduction of tetraphenylcyclopentadienones

✍ Scribed by Haluk Özyörük; Kadi̇r Pekmez; Atti̇lla Yildiz

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
402 KB
Volume
32
Category
Article
ISSN
0013-4686

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✦ Synopsis

The electroreduction behavior of tetraphenylcyclopentadienone (tetracyclone) and some of its m,m'-and p,p'-substituted derivatives in acetonitrile was investigated. The mechanism for the electroreduction of these compounds in the absence and in the presence. of protons was proposed using the results of cyclic voltammetry and controlled Potential electrolysis experiments. The effects of the substitution on the peak potentials and on the stability of the anion radicals are discussed.

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