Electrochemical reduction of tetraalkylammonium tetrafluoroborates at carbon cathodes in dimethylformamide
β Scribed by Christopher E. Dahm; Dennis G. Peters
- Publisher
- Elsevier
- Year
- 1996
- Tongue
- English
- Weight
- 535 KB
- Volume
- 402
- Category
- Article
- ISSN
- 1572-6657
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π SIMILAR VOLUMES
The reduction of methyl, ethyl, n-propyl and n-butyl iodides has been studied at a tin cathode in dimethylformamide. The major product from the reduction of methyl iodide is tetramethyl tin but from ethyl, propyl and butyl iodides it is butane, hexane and oxtane respectively. Also as the size of the
In acetonitrile containing tetraethyhunmonium perchlorate, cyclic voltammograms for the reduction of 2,4,6-trimethylbenxoyl chloride at glassy carbon and hanging mercury drop electrodes exhibit five and four cathodic waves, respectively. At potentials corresponding to the first wave, cleavage of the