Electrochemical reduction of sulfur in aprotic solvents
β Scribed by Martin, Robert P.; Doub, William H.; Roberts, Julian L.; Sawyer, Donald T.
- Book ID
- 127295439
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 627 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
Since the original report by Mairanovskii and Neimanl,. several groups have investigated the electrochemistry of sulfones; however, most of the work has been in protic solvents. In such media the mechanism for the reduction of diphenyl sulfone is generally reported to be a two electron transfer with
The oxidation-reduction behaviour of 2,2'-dinitrobiphenyl-X type compounds (X = 0, S, NH, CH,, CO) and of 2,2'-dinitrobiphenyl in non-aqueous acetonitrile and dimethylformamide and their mixtures with water was investigated by polarography and cyclic voltammetry at mercury drop electrodes. In combin