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Electrochemical reduction of some α-substituted nitroalkanes

✍ Scribed by Janet C. Rühl; Dennis H. Evans; Pedatsur Neta


Publisher
Elsevier
Year
1992
Tongue
English
Weight
944 KB
Volume
340
Category
Article
ISSN
1572-6657

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Electrochemical reduction of 1,2,4,6-sub
✍ J. Volke; J. Urban; V. Volkeová 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 360 KB

In aprotic solvents such as dimethylformamide, acetonitrile or dimethylsulphoxide, the mechanism of electrochemical reduction of 1,2,4,6-substituted pyridinium cations was investigated. The stability of the key intermediate in the overall two-electron reduction, ie of the neutral radical, was increa