When the concentration of (I) is above ~ 1 x 10 4 M, the polarogram exhibits a further wave, distinguishable from the current rise due to the discharge of the supporting electrolyte only between pH 8 and 11.
Electrochemical reduction of azomethine derivatives of α-diketones: III. 1,2-dihydropyrrolizine-1,2-dione dioxime
✍ Scribed by Mario E. Cardinali; Italo Carelli; Antonio Trazza
- Publisher
- Elsevier Science
- Year
- 1973
- Weight
- 351 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0022-0728
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The electroreduction of 2,2,2-trichloro-l-phenylethyl derivatives (VIII) in aqueous dmf yields fl,&dichlorostyrene (VII) and/or the corresponding 2,2-dichloro-1-phenylethyl derivatives (IX). For the set of compounds thus far investigated, there is a strong dependence: ot the product distribution as
Comparative studies of the electrochemical reduction of 2-(o-nitrophenylthio)-acetic acid and its methyl ester in aqueous media of different acidity show that reduction of the ester in an ammoniacal buffer is the best adapted for ekctrosynthesis of 4-hydroxy-2H-1,4-benzothiazin-3(4H)-one. The electr