Electrochemical reduction of 3-diazocamphor
โ Scribed by Mario Emilio Cardinali; Italo Carelli; Antonio Trazza
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 844 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0022-0728
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โฆ Synopsis
Badly-separated wave. ** Ill-defined wave.
๐ SIMILAR VOLUMES
In the absence of NaC1 the two waves observed in an alkaline medium are even less reSolved, and the total limiting current decreases steadily at potentials more negative than -1.3 V. \*\* See later coulometric results.
In DMF KC104 2.0 x 10-2 F the discharge begins at about -1.90 V. If the same solution contains also 2.0 ร 10 -4 F CH/C1COOH the discharge begins at about -1.75 V.
Electrochemical reduction ofcyclic and acyclic derivatives of 2,3-butanediol lo C,-hydrocarbons was examined. Among the derivatives, the cyclic sulphate was directly reduced to 2-butene; thediacatatc and dimethanesulphonatc also gave 2-butene but by indirect reduction with electrogenerated amalgam.