Electrochemical Reduction of 2,2,2-Trichloroethanols

✍ Scribed by Dr. Andreas Merz

• Publisher: John Wiley and Sons
• Year: 1977
• Tongue: English
• Weight: 225 KB
• Volume: 16
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.197700571

✦ Synopsis

bly chromium-the examples are few and far between. The higher homologs, molybdenum and tungsten, on the other hand, readily bind nitrogen and can even coordinate two N2-ligands[" 21. To our knowledge, such complexes with metals of the first transition series have not as yet been reportedf3].

During investigations on the behavior of trimethylphosphane in the presence of low-valency metals[4] it was found that the complex c ~s -[ ( C H ~) ~P ) ] ~C ~( N , ) ~