Electrochemical Reduction of 2-Nitroanisole in Ionic Liquid BMIm-BF4: Synthesis of 2-Anisidine
✍ Scribed by Ying-Zi LIU; Mei-Yu LIN; Li-Ping XIAO; Kai ZHANG; Jia-Xing LU
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 75 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0256-7660
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The electrochemical reduction-Bamberger substitution of 2nitroanisole in 1 M H 2 SO 4 yields predominantly 2,5-dimethoxyaniline, not the expected 2,4-isomer. The selectivity was found to be acid-and solvent-dependent, with lower acidity and less polar solvents favoring the formation of 2,4-
## Abstract magnified image The one‐pot direct synthesis of 2‐aminobenzothiazoles from phenyl isothiocyanate and amines using a new reagent of 1‐butyl‐3‐methylimidazolium tribromide ([Bmim]Br~3~) in ionic liquid 1‐butyl‐3‐methylimidazolium tetraflouoroborate ([Bmim]BF~4~) is described.