Electrochemical properties of 2,2":6",2″-terpyridine complexes of platinum(ii) with arenethiolate ligands. Alkylation of reduced forms of the complexes
✍ Scribed by R. D. Rakhimov; Yu. A. Weinstein; E. V. Lileeva; N. N. Zheligovskaya; M. Ya. Mel'nikov; K. P. Butin
- Book ID
- 111546162
- Publisher
- Springer
- Year
- 2003
- Tongue
- English
- Weight
- 372 KB
- Volume
- 52
- Category
- Article
- ISSN
- 1573-9171
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The complex [Pt(Cl 3 terpy)Cl]PF 6 has been prepared from cis-[Pt(dimethylsulfoxide) 2 Cl 2 ] and 4,4%,4¦-trichloro-2,2%:6%,2¦-terpyridine (Cl 3 terpy). The complex [Pt(Clterpy)Cl]Cl has been prepared from cis-[Pt (1,5-cyclooctadiene)Cl 2 ] and 4%-chloro-2,2%:6%,2¦terpyridine (Clterpy). Complexes ha
Platinum(II) chloride can selectively be coordinated to the 2,2'-bipyridine moiety of the alkyl bridged sequential catechol/2,2'-bipyridine ligand 1 a-H 2 and of the related ligands 1 a/b-Me 2 and 2. Reaction of (1 b-Me 2 )PtCl 2 with BBr 3 produces the platinum(II) complex (1 b-H 2 )PtCl 2 while et